BUG #11401: When I comparison geting of field returns false, but when I do directly with result returns true

The following bug has been logged on the website:

Bug reference: 11401
Logged by: Natan Medeiros
Email address: natan(at)logicasistemas(dot)com(dot)br
PostgreSQL version: 9.1.14
Operating system: Debian
Description:

Hi everyone,

I'm trying to do a query and stops in source below:

btrim = clean spaces

upper = a -> A

pcc.mac returns "" (null)

pcc.username returns "SIMONE.GISELIA"

btrim(upper(pcc.mac::character varying::text)) <>
btrim(upper(pcc.username::text))

if I put the code above, the postgres understand as false, but if I put the
code below returns true, why?

SELECT CASE WHEN "" <> "SIMONE.GISELIA" THEN true ELSE false end

Both fields returns different text and the result is false and shouldn't.

I'm stuck on that and don't know what do.

I need to compare this options, if don't, the source not work.

If anyone could help me I will be glad for that.